Solvent-induced configuration mixing and triplet excited state inversion exemplified in a Pt(II) complex

被引:32
作者
Goeb, Sebastien
Rachford, Aaron A.
Castellano, Felix N. [1 ]
机构
[1] Bowling Green State Univ, Dept Chem, Bowling Green, OH 43403 USA
关键词
D O I
10.1039/b713285a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present study provides clear-cut experimental evidence for solvent-induced configuration mixing and complete triplet state inversion at room temperature in a Pt(II) charge transfer complex bearing a combination of energetically proximate charge transfer and intraligand triplet excited states.
引用
收藏
页码:814 / 816
页数:3
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