Novel anion binding selectivity trends exhibited by new dinuclear rhenium(I), ruthenium(II) and osmium(II) bipyridyl cleft-type receptors

被引:41
作者
Beer, PD [1 ]
Dent, SW [1 ]
Hobbs, GS [1 ]
Wear, TJ [1 ]
机构
[1] KODAK LTD,HARROW HA1 4TY,MIDDX,ENGLAND
关键词
D O I
10.1039/a607086h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel dinuclear rhenium(I), ruthenium(II) and osmium(II) bipyridyl cleft-type receptor systems exhibit remarkable selectivity for dihydrogenphosphate over halide anions dictated by the nature of the bridging linkage and the transition-metal Lewis-acidic centre.
引用
收藏
页码:99 / 100
页数:2
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