Enantioselective synthesis of sabina ketone

被引:18
作者
Barberis, M [1 ]
Pérez-Prieto, J [1 ]
机构
[1] Univ Valencia, ICMOL, Dept Quim Organ, E-46100 Valencia, Spain
关键词
sabina ketone; dirhodium(II) compounds; asymmetric synthesis;
D O I
10.1016/S0040-4039(03)01629-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Both enantiomers of sabina ketone were efficiently prepared via an easy synthesis of 1-diazo-5-methylene-6-methylheptan-2-one, starting from succinic anhydride, followed by its highly enantioselective cyclization catalyzed by chiral dirhodium(II) compounds having ortho-metalated phosphines as ligands. (C) 2003 Published by Elsevier Ltd.
引用
收藏
页码:6683 / 6685
页数:3
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