Zn(II)-catalyzed thiolysis of oxiranes in water under neutral conditions

被引：102

作者：

Fringuelli, F ^{[1
]}

Pizzo, F ^{[1
]}

Tortoioli, S ^{[1
]}

Vaccaro, L ^{[1
]}

机构：

[1] Univ Perugia, Dipartimento Chim, I-06100 Perugia, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 21期

关键词：

D O I：

10.1021/jo0348266

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thiolysis of a variety of 1,2-epoxides in water at 30degreesC and pH 7.0 is strongly accelerated by ZnCl(2) (10 mol %) except when amino- and carboxythiophenol are used. The aqueous medium and the catalyst were recovered and reused in various runs without affecting the efficiency of the process.

引用

页码：8248 / 8251

页数：4

共 57 条

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