Chloroaluminate(III) ionic liquid mediated synthesis of transition metal-cyclophane complexes: their role as solvent and Lewis acid catalyst

被引：35

作者：

Crofts, D ^{[1
]}

Dyson, PJ ^{[1
]}

Sanderson, KM ^{[1
]}

Srinivasan, N ^{[1
]}

Welton, T ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 573卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

ionic liquid; aluminium chloride; cyclophane; metal-arene complexes;

D O I：

10.1016/S0022-328X(98)00734-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of transition metal-cyclophane complexes using the ionic liquid system [bmim]Cl-AlCl3 ([bmim](+) = 1-butyl-3-methylimidazolium cation) as both the solvent and Lewis acid catalyst is described. Both known and novel complexes are prepared. Simple arene complexes of manganese have also been prepared in order to demonstrate the chemistry and these reactions are compared with the literature preparations conducted in conventional organic solvents. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：292 / 298

页数：7

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