Chloroaluminate(III) ionic liquid mediated synthesis of transition metal-cyclophane complexes: their role as solvent and Lewis acid catalyst

被引：35

作者：

Crofts, D ^{[1
]}

Dyson, PJ ^{[1
]}

Sanderson, KM ^{[1
]}

Srinivasan, N ^{[1
]}

Welton, T ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 573卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

ionic liquid; aluminium chloride; cyclophane; metal-arene complexes;

D O I：

10.1016/S0022-328X(98)00734-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of transition metal-cyclophane complexes using the ionic liquid system [bmim]Cl-AlCl3 ([bmim](+) = 1-butyl-3-methylimidazolium cation) as both the solvent and Lewis acid catalyst is described. Both known and novel complexes are prepared. Simple arene complexes of manganese have also been prepared in order to demonstrate the chemistry and these reactions are compared with the literature preparations conducted in conventional organic solvents. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：292 / 298

页数：7

共 23 条

[11]

Hussey C. L., 1983, Adv. Molten Salt Chem, V5, P185, DOI DOI 10.1039/B601395C

[12] (ARENE)TRICARBONYLMANGANESE(I) COMPLEXES - A PREPARATIVE STUDY - CRYSTAL-STRUCTURE OF [(ETA-6-C6H5CH2COCH2PH)MN(CO)3]BF4 [J].

JACKSON, JD ;

VILLA, SJ ;

BACON, DS ;

PIKE, RD ;

CARPENTER, GB .

ORGANOMETALLICS, 1994, 13 (10) :3972-3980

[13] REACTIVITY OF TRICARBONYL(ARENE)MANGANESE(I) AND TRICARBONYL(ARENE)RHENIUM(I) CATIONS - NUCLEOPHILIC-ADDITION OF TRIBUTYLPHOSPHINE TO THE ARENE AND NUCLEOPHILIC DISPLACEMENT OF THE ARENE BY ACETONITRILE [J].

KANEMAGUIRE, LAP ;

SWEIGART, DA .

INORGANIC CHEMISTRY, 1979, 18 (03) :700-706

[14]

NESMEYANOV AN, 1974, IAN SSSR KH, V9, P2159

[15] REMOVAL OF PROTONS FROM AMBIENT-TEMPERATURE CHLOROALUMINATE IONIC LIQUIDS [J].

NOEL, MAM ;

TRULOVE, PC ;

OSTERYOUNG, RA .

ANALYTICAL CHEMISTRY, 1991, 63 (24) :2892-2896

[16] PREPARATION AND REACTIVITY OF ETA-6-VERATROLEMANGANESE TRICARBONYL TETRAFLUOROBORATE [J].

PEARSON, AJ ;

RICHARDS, IC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 258 (02) :C41-C44

[17]

RUBINSKAYA MI, 1984, IZV AKAD NAUK SSSR A, P885

[18] ARENE COMPLEXES OF UNIVALENT GALLIUM, INDIUM, AND THALLIUM [J].

SCHMIDBAUR, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (11) :893-904

[19]

SILVERTHORN WE, 1975, ADV ORGANOMETALLIC C, V13, P47, DOI DOI 10.1016/S0065-3055(08)60682-6

[20] (ETA(6)-POLYARENE)MN(CO)3(+) COMPLEXES AS MANGANESE TRICARBONYL TRANSFER REAGENTS - A CONVENIENT AND GENERAL SYNTHETIC ROUTE TO (ARENE)MN(CO)3(+) COMPLEXES [J].

SUN, SH ;

YEUNG, LK ;

SWEIGART, DA ;

LEE, TY ;

LEE, SS ;

CHUNG, YK ;

SWITZER, SR ;

PIKE, RD .

ORGANOMETALLICS, 1995, 14 (06) :2613-2615

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