Ammonium decatungstocerate (IV): an efficient catalyst for ring opening of epoxides with aromatic amines

被引：20

作者：

Mirkhani, V ^{[1
]}

Tangestaninejad, S

Yadollahi, B

Alipanah, L

机构：

[1] Isfahan Univ, Dept Chem, Esfahan 8174673441, Iran

[2] Inst Adv Studies Basic Sci, Gava Zang 4513879368, Zanjan, Iran

来源：

CATALYSIS LETTERS | 2005年 / 101卷 / 1-2期

关键词：

ring opening; epoxides; catalysis; aromatic amines; aminolysis;

D O I：

10.1007/s10562-004-3755-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mild, convenient and efficient ring opening of oxiranes with aromatic amines was catalyzed by ammonium decatungstocerate (IV) in acetonitrile. The reaction afforded the corresponding products in 92 - 100% yields. The catalyst was reused for several times with consistent activity. [GRAPHICS]

引用

收藏

页码：93 / 97

页数：5

相关论文

共 41 条

[1] 1,2-amino alcohols and their heterocyclic derivatives as chiral auxiliaries in asymmetric synthesis [J].

Ager, DJ ;

Prakash, I ;

Schaad, DR .

CHEMICAL REVIEWS, 1996, 96 (02) :835-875

[2] TRICHOGIN-A-IV, AN 11-RESIDUE LIPOPEPTAIBOL FROM TRICHODERMA-LONGIBRACHIATUM [J].

AUVINGUETTE, C ;

REBUFFAT, S ;

PRIGENT, Y ;

BODO, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) :2170-2174

[3] IMMOBILIZED TRANSITION-METAL CARBONYLS AND RELATED CATALYSTS [J].

BAILEY, DC ;

LANGER, SH .

CHEMICAL REVIEWS, 1981, 81 (02) :109-148

[4] ENANTIOSELECTIVE REDUCTION OF KETONES CATALYZED BY 1,3,2-OXAZABOROLIDINES PREPARED FROM PHENYLGLYCINE [J].

BERENGUER, R ;

GARCIA, J ;

VILARRASA, J .

TETRAHEDRON-ASYMMETRY, 1994, 5 (02) :165-168

[5] REGIOSELECTIVE AND CHEMOSELECTIVE SYNTHESIS OF HALOHYDRINS BY CLEAVAGE OF OXIRANES WITH METAL-HALIDES [J].

BONINI, C ;

RIGHI, G .

SYNTHESIS-STUTTGART, 1994, (03) :225-238

[6] ORGANOBORANES .53. A HIGH-FIELD VARIABLE-TEMPERATURE H-1 AND B-11 NMR-STUDY OF THE EFFECTS OF SOLVENT AND STRUCTURE ON REACTIVITY IN ALLYLBORATION [J].

BROWN, HC ;

RACHERLA, US ;

PELLECHIA, PJ .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (06) :1868-1874

[7] LANTHANIDE(III) TRIFLUOROMETHANESULFONATES AS EXTRAORDINARILY EFFECTIVE NEW CATALYSTS FOR THE AMINOLYSIS OF 1,2-EPOXIDES [J].

CHINI, M ;

CROTTI, P ;

FAVERO, L ;

MACCHIA, F ;

PINESCHI, M .

TETRAHEDRON LETTERS, 1994, 35 (03) :433-436

[8] Solution-phase synthesis of a beta-amino alcohol combinatorial library [J].

Chng, BL ;

Ganesan, A .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1997, 7 (12) :1511-1514

[9] 1,2,3-OXATHIAZOLIDINES - A NEW HETEROCYCLIC SYSTEM [J].

DEYRUP, JA ;

MOYER, CL .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (01) :175-&

[10] A regio- and stereoselective synthesis of beta-amino alcohols [J].

Fu, XL ;

Wu, SH .

SYNTHETIC COMMUNICATIONS, 1997, 27 (10) :1677-1683

← 1 2 3 4 5 →