Functional models for the oxygen-evolving complex of photosystem II

被引：346

作者：

Cady, Clyde W. ^{[1
]}

Crabtree, Robert H. ^{[1
]}

Brudvig, Gary W. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 3-4期

关键词：

oxomanganese clusters; oxygen evolution; ruthenium; water oxidation;

D O I：

10.1016/j.ccr.2007.06.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the last 10 years, a number of advances have been made in the study of the oxygen-evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the natural system has come rapid advance in chemical models of this system. The advance of PSII model chemistry is seen most strikingly in the area of functional models where the few known systems available when this topic was last reviewed has grown into two families of model systems. In concert with this work, numerous mechanistic proposals for photosynthetic water oxidation have been proposed. Here, we review the recent efforts in functional model chemistry of the oxygen-evolving complex of photosystem II. (c) 2007 Elsevier B.V. All rights reserved.

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页码：444 / 455

页数：12

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