Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures

被引：28

作者：

Leoni, P ^{[1
]}

Marchetti, F ^{[1
]}

Marchetti, L ^{[1
]}

Pasquali, M ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 18期

关键词：

D O I：

10.1039/b307003d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between the new hexa- and trinuclear clusters {Pt-6}(CC-C6H4-CCH)(2), (4) [{Pt-6} = Pt-6(CO)(4)(mu-PBu2t)(4)], and {Pt-3}Cl, (6) [{Pt-3} = Pt-3(mu-PBu2t)(3)(CO)(2)], in CuI/Amine gives the thermally and air stable {Pt-6}(CC-C6H4-CC{Pt-3})(2) (7), where the cluster units are separated by conjugated 1,4-diethynylphenyl groups.

引用

页码：2372 / 2373

页数：2

共 50 条

[1] Cluster compounds containing a linear carbon chain derived from polyynediyl and polyynyl complexes, Fp*-(CC)n-X [X = Fp*, H; Fp* = Fe(η5-C5Me5)(CO)2] [J].

Akita, M ;

Sakurai, A ;

Chung, MC ;

Moro-oka, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 670 (1-2) :2-10

[2] Synthesis of neutral tetranuclear and octanuclear macrocyclic platinum-butadiyne heterocyclynes [J].

ALQaisi, SM ;

Galat, KJ ;

Chai, MH ;

Ray, DG ;

Rinaldi, PL ;

Tessier, CA ;

Youngs, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :12149-12150

[3] Synthesis of linear oligomers of [1,3-diethynyl-2,4-bis(trimethylsilyl)cyclobutadiene]cyclopentadienylcobalt: Dimer to nonamer [J].

Altmann, M ;

Enkelmann, V ;

Beer, F ;

Bunz, UHF .

ORGANOMETALLICS, 1996, 15 (01) :394-399

[4] POLYMERS WITH COMPLEXED CYCLOBUTADIENE UNITS IN THE MAIN-CHAIN - THE FIRST EXAMPLE OF A THERMOTROPIC, LIQUID-CRYSTALLINE ORGANOMETALLIC POLYMER [J].

ALTMANN, M ;

BUNZ, UHF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (05) :569-571

[5]

BARTLEY SL, 2003, J CHEM SOC DA, P2937

[6] Polycarbon ligand complexes:: Synthesis, molecular structures, and selected EHMO studies of Ru4, Ru5, and Ru6 clusters with carbon ligands derived from phosphinodiynes [J].

Blenkiron, P ;

Enright, GD ;

Low, PJ ;

Corrigan, JF ;

Taylor, NJ ;

Chi, Y ;

Saillard, JY ;

Carty, AJ .

ORGANOMETALLICS, 1998, 17 (12) :2447-2458

[7] ISOCYANIDE AND DIISOCYANIDE COMPLEXES OF A TRIPLATINUM CLUSTER - FLUXIONALITY, ISOMERISM, STRUCTURE, AND BONDING [J].

BRADFORD, AM ;

KRISTOF, E ;

RASHIDI, M ;

YANG, DS ;

PAYNE, NC ;

PUDDEPHATT, RJ .

INORGANIC CHEMISTRY, 1994, 33 (11) :2355-2363

[8] A new approach to the synthesis of carbon chains capped by metal clusters [J].

Bruce, MI ;

Smith, ME ;

Zaitseva, NN ;

Skelton, BW ;

White, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 670 (1-2) :170-177

[9] Some molecular rods:: gold(I) complexes of 1,3-diynes.: Crystal structures of Au(C≡CC≡CH)(PPh3) and {Cu3(μ-dppm)3}(μ3-I)(μ3-C≡CC≡CAuC≡CC≡CH) [J].

Bruce, MI ;

Hall, BC ;

Skelton, BW ;

Smith, ME ;

White, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06) :995-1001

[10] Some complexes of all-carbon ligands and related chemistry [J].

Bruce, MI .

COORDINATION CHEMISTRY REVIEWS, 1997, 166 :91-119

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