共 12 条
Oxidation of dimethylplatinum(II) complexes with dioxygen
被引:69
作者:
Rostovtsev, VV
Labinger, JA
Bercaw, JE
Lasseter, TL
Goldberg, KI
[1
]
机构:
[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synthesis, Pasadena, CA 91125 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词:
D O I:
10.1021/om980541l
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Dimethylplatinum(II) complexes (L-L)Pt-(CH3)(2) (L-L = bpy, phen, tmeda) are oxidized by dioxygen in methanol to the corresponding alkoxoplatinum(IV) complexes (L-L)Pt(CH3)(2)(OH)(OCH3).
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页码:4530 / 4531
页数:2
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