An efficient method for the preparation of bismuth(III) trifluoromethanesulfonate

被引:88
作者
Labrouillère, M [1 ]
Le Roux, C [1 ]
Gaspard, H [1 ]
Laporterie, A [1 ]
Dubac, J [1 ]
Desmurs, JR [1 ]
机构
[1] Univ Toulouse 3, CNRS, Lab, F-31062 Toulouse, France
关键词
D O I
10.1016/S0040-4039(98)02397-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Bismuth(lll) trifluoromethanesulfonate (Bi(OTf)(3) 1) can be easily prepared from the reaction of protiodemetallation of triphenylbismuth by a stoichiometric amount of trifluoromethanesulfonic acid The intermediates Ph3-nBi(OTf)(n) [n=2(2) 1(3)] have been isolated This process represents an improvement of the previously reported methods. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:285 / 286
页数:2
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