High enantioselectivity in the electron transfer reaction between a Ru(II) complex of menbpy anion radical, [Ru(menbpy)3]+ [menbpy = 4,4′-di{(1R,2S,5R)-(-)-menthoxycarbonyl}-2,2′-bipyridine] and [Co(acac)3]:: A pulse radiolysis study

被引：5

作者：

Hamada, T

Sakaki, S ^{[1
]}

Brunschwig, BS

Fujita, E

Wishart, JF

机构：

[1] Kumamoto Univ, Fac Engn, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan

[2] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

CHEMISTRY LETTERS | 1998年 / 12期

关键词：

D O I：

10.1246/cl.1998.1259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-electron reduction of [Ru(menbpy)(3)](2+) [menbpy = 4,4'- di{(1R,2S,SR)- (-)- menthoxycarbonyl}-2,2'-bipyridine] by pulse radiolysis produces a Ru(II) complex of a menbpy-centered anion radical, which reduces Delta-[Co(acac)(3)] more rapidly than Lambda-[Co(acac)(3)] with an enantioselectivity of 2.7 in 85% EtOH/H2O.

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页码：1259 / 1260

页数：2

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