Synthesis of textured thermoelectric layered cobaltites by reactive templated grain growth

被引：7

作者：

Itahara, H ^{[1
]}

Xia, C ^{[1
]}

Seno, Y ^{[1
]}

Sugiyama, J ^{[1
]}

Tani, T ^{[1
]}

Koumoto, K ^{[1
]}

机构：

[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

来源：

TWENTY-SECOND INTERNATIONAL CONFERENCE ON THERMOELECTRICS, PROCEEDINGS ICT '03 | 2003年

关键词：

D O I：

10.1109/ICT.2003.1287480

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In order to apply layered cobaltites to thermoelectric (TE) devices, we need aligned ceramics to exploit their superior in-plane TE properties. Here, we report the preparation and characterization of c-axis aligned [Ca2CoO3](0.62)[CoO2] (CCO) ceramics by the reactive templated grain growth (RTGG) method. As reactive templates, we synthesized platelike beta-Co(OH)(2) particles by a precipitation method. The template particles were mixed with a complementary reactant, CaCO3, and aligned by a tape-casting. Upon heat treatment, they reacted to form a CCO ceramic with almost perfectly c-alignment (Lotgering's orientation degree, f > 0.99). The highly textured ceramic shows significantly large in-plane electrical conductivity (sigma(ab)): i.e., the value of sigma(ab) was 2.61 x 104 S/m at 1060 K, where the value is around 60% of that of a single crystal. We conclude that the RTGG method must be an effective and versatile technique for the preparation of large-sized TE materials with high TE performances.

引用

页码：188 / 191

页数：4