Electrochemical polymerization of 3,4-ethylenedioxythiophene in a DNA liquid-crystal electrolyte

被引：33

作者：

Goto, H

Nomura, N

Akagi, K ^{[1
]}

机构：

[1] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci, Tsukuba, Ibaraki 3058573, Japan

[2] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan

[3] Univ Tsukuba, Inst Appl Biochem, Tsukuba, Ibaraki 3058572, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2005年 / 43卷 / 18期

关键词：

chiral; composites; conjugated polymers; matrix; molecular imprinting;

D O I：

10.1002/pola.20909

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The electrochemical polymerization of 3,4-ethylenedioxythiophene (EDOT) in DNA liquid-crystal (LC) electrolyte was analyzed. A custom-made three-electrode cell was used for the asymmetric oxidative electrochemical polymerization. The DNA electrolyte containing the monomer (EDOT) was charged between the sandwiched electrodes, where a Teflon sheet was inserted as a spacer. The electrochemical polymerization of EDOT in the oligonucleotides showing no lyotropic LC gave neither a specific surface morphology nor optical activity for the polymer film.

引用

页码：4298 / 4302

页数：5

共 19 条

[1] Helical polyacetylene synthesized with a chiral nematic reaction field [J].