Synthesis and characterisation of the first carbene-thallium complexes:: molecular structure of [TiCl3{CN(Mes)C2H2N(Mes)}], Mes = C6H2Me3-2,4,6

被引：31

作者：

Cole, ML ^{[1
]}

Davies, AJ ^{[1
]}

Jones, C ^{[1
]}

机构：

[1] Univ Wales, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b105322c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the stable carbenes,:CN(Mes)C2R2N(Mes), R = H (IMes) or Br (IMesBr), with TlX3, X = Cl or Br, Mes = mesityl, yields the complexes, [TlX3, {CN(Mes)-C2R2N(Mes)}], one of which, [TlCl3(IMes)], has been crystallographically characterised and its thermal decomposition studied; further reaction of [TlCl3(IMes)] with one equivalent of :CN(Me)C2Me2N(Me) affords the mixed bis-carbene complex [TlCl3(IMes){CN(Me)C2Me2N(Me)}] which has been characterised spectroscopically.

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页码：2451 / 2452

页数：2

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