Metalloporphyrin catalyzed asymmetric cyclopropanation of olefins

被引：111

作者：

Gross, Z ^{[1
]}

Galili, N ^{[1
]}

Simkhovich, L ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(98)02647-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric cyclopropanation of styrene by an enantiopure carbenoid under catalysis by simple metalloporphyrins was found to be much more efficient and selective than the alternative approach, the combination of metal complexes of enantiopure porphyrins and a non-chiral diazoester. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1571 / 1574

页数：4

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