Structural changes accompanying the stepwise population of a B-C π bond

被引：66

作者：

Chiu, Ching-Wen ^{[1
]}

Gabbaie, Francois P. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 36期

关键词：

boron; multiple bonds; NBO analysis; reduction;

D O I：

10.1002/anie.200702299

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Get Shorty: The central boron-carbon bond of an α-borylated carbocation undergoes a noticeable shortening upon reduction by one and two electrons, and the degree of twisting about this bond is also noticeably reduced (see graph). According to both experiment and theory, these effects result from the sequential population of the central boron-carbon π bond. (Graph Presented). © 2007 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：6878 / 6881

页数：4

共 21 条

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