Accurate first-principle equation of state for the one-component plasma

被引:41
作者
Brilliantov, NV [1 ]
机构
[1] Univ Toronto, Chem Phys Theory Grp, Dept Chem, Toronto, ON M5S 3H6, Canada
[2] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119899, Russia
关键词
D O I
10.1002/ctpp.2150380403
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
Accurate "first-principle" expressions for the excess free energy F(ex) and internal energy of U(ex) of the classical one-component plasma (OCP) are obtained. We use the Hubbard-Schofield transformation that maps the OCP Hamiltonian onto the Ising-like Hamiltonian, with coefficients expressed in terms of equilibrium correlation functions of a reference system. We use the ideal gas as a reference system for which all the correlation functions are known. Explicit calculations are performed with the high-order terms in the Ising-like Hamiltonian omitted. For small values of the plasma parameter Gamma the Debye-Huckel result for F(ex) and U(ex) is recovered. For Gamma much greater than 1, these depend linearly on Gamma in accordance with the Monte Carlo findings for the OCP. The MC data for the internal energy are reproduced fairly well by the expression for U(ex) obtained.
引用
收藏
页码:489 / 499
页数:11
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