Ynolates as functional carbanions

被引：46

作者：

Shindo, M

机构：

[1] Univ Tokushima, Inst Med Resources, Tokushima 7708505, Japan

[2] Japan Sci & Technol Corp, PRESTO, Kawaguchi, Saitama 3320072, Japan

来源：

SYNTHESIS-STUTTGART | 2003年 / 15期

关键词：

carbanions; cycloadditions; tandem reactions; ynolates; olefination;

D O I：

10.1055/s-2003-42417

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ynolates are multifunctional carbanions bearing a triple bond. Due to the difficulty in synthesizing them, their chemistry has remained relatively unexplored. However, since the recent publication of several new methodologies for the preparation of these interesting compounds, the versatility of ynolates in synthetic organic chemistry has been recognized, and new aspects of ynolate chemistry, e.g., tandem reactions, cycloadditions, olefinations of carbonyl compounds, are being developed.

引用

收藏

页码：2275 / 2288

页数：14

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