Fabrication and structural characteristics of ordered TiO2-Ru(-RuO2) nanorods in porous anodic alumina films on ITO/glass substrate

被引：32

作者：

Chu, SZ ^{[1
]}

Wada, K ^{[1
]}

Inoue, S ^{[1
]}

Hishita, S ^{[1
]}

Kurashima, K ^{[1
]}

机构：

[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2003年 / 107卷 / 37期

关键词：

D O I：

10.1021/jp0354503

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ordered nanorod (similar tophi50 nm) arrays of TiO2-Ru and TiO2-RuO2 embedded in porous alumina films were prepared from sputtered Al/ITO films on glass substrates through successive processes of anodization and cathodic electrodeposition. The microstructure of the nanorod arrays was investigated by field-emission scanning electron microscopy and transmission electron microscopy, and the chemical states of the titanium and ruthenium elements in the nanorods were analyzed through X-ray photoelectron spectroscopy. The as-electrodeposited nanorods are composed of ruthenium metal and amorphous titanium(IV) oxide/hydroxide, while the nanorods after being heated at 600 degreesC for 2 h are polycrystalline and composed of nano-crystals (5-20 nm across) of tetragonal anatase TiO2 and cubic RuO2.

引用

页码：10180 / 10184

页数：5

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