Novel spinel oxide Li4/3Ti5/3O4 as electrochemical insertion materials for rechargeable lithium batteries

被引：27

作者：

Kanamura, K

Naito, H

Takehara, Z

机构：

[1] Dept. of Ener. and Hydrocarbon Chem., Graduate School of Engineering, Kyoto University, Kyoto 606-01, Sakyo-ku

来源：

CHEMISTRY LETTERS | 1997年 / 01期

关键词：

D O I：

10.1246/cl.1997.45

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We firstly claim that the unique performance of Li4/3Ti5/3O4 as electrochemical materials in terms of a flat potential and an infinitesimal structural change is caused by a cation ordering of Li+ and Ti4+ at 16d sites in the spinel superstructure.

引用

页码：45 / 46

页数：2

共 20 条

[1] STRUCTURE AND ELECTROCHEMISTRY OF THE SPINEL OXIDES LITI2O4 AND LI4/3TI5/3O4
COLBOW, KM
DAHN, JR
HAERING, RR
[J]. JOURNAL OF POWER SOURCES, 1989, 26 (3-4) : 397 - 402
[2] RECHARGEABLE LINIO2 CARBON CELLS
DAHN, JR
VONSACKEN, U
JUZKOW, MW
ALJANABY, H
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) : 2207 - 2211
[3] SPINEL ANODES FOR LITHIUM-ION BATTERIES
FERG, E
GUMMOW, RJ
DEKOCK, A
THACKERAY, MM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) : L147 - L150
[4] THE SUPERCONDUCTOR-SEMICONDUCTOR TRANSITION IN THE LI1+XTI2-XO4 SPINEL SYSTEM
HARRISON, MR
EDWARDS, PP
GOODENOUGH, JB
[J]. PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1985, 52 (03): : 679 - 699
[5] Structural change of the LiMn2O4 spinel structure induced by extraction of lithium
Kanamura, K
Naito, H
Yao, T
Takehara, Z
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (01) : 33 - 36
[6] KOSHIBA N, 1994, DENKI KAGAKU, V62, P970
[7] KOSHIBA N, 1994, DENKI KAGAKU, V62, P870
[8] Mosbah A., 1983, Materials Research Bulletin, V18, P1375, DOI 10.1016/0025-5408(83)90045-4
[9] ZERO-STRAIN INSERTION MATERIAL OF LI[LI1/3TI5/3]O-4 FOR RECHARGEABLE LITHIUM CELLS
OHZUKU, T
UEDA, A
YAMAMOTO, N
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (05) : 1431 - 1435
[10] ELECTROCHEMISTRY AND STRUCTURAL CHEMISTRY OF LINIO2 (R(3)OVER-BAR-M) FOR 4 VOLT SECONDARY LITHIUM CELLS
OHZUKU, T
UEDA, A
NAGAYAMA, M
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (07) : 1862 - 1870

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