Synthesis and characterization of oxo- and thiophosphorylcyclopentadienyl Ti(IV) thiolate complexes.: Crystal structures of [(η5-C5H4P(S)Ph2)(η5-C5H4SiMe3)TiCl2] and [(η5-C5H4P(S)Ph2)2Ti(SPh)2]•C4H10O

被引：10

作者：

Delgado, E ^{[1
]}

Garcia, MA

Hernandez, E

Mansilla, N

Martinez-Cruz, LA

Tornero, J

Torres, R

机构：

[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Inorgan, Madrid 20249, Spain

[2] CSIC, Inst Quim Fis Rocasolano, Dept Cristalog, E-28006 Madrid, Spain

[3] Univ Autonoma Madrid, Serv Interdept Invest Rayos X, E-28049 Madrid, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 560卷 / 1-2期

关键词：

titanium; thiolate; cyclopentadienyl;

D O I：

10.1016/S0022-328X(98)00496-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New titanium (IV) complexes containing diphenyloxo- or diphenylthiophosphorylcyclopentadienyl ligands are obtained by reaction of diphenylphosphinocyclopentadienyl derivatives with the appropriate oxidizer (S-8 or H2O2). The crystal structures of [(eta(5)-C5H4P(S)Ph-2)(eta(5)-C5H4SiMe3)TiCl2] 3 and [(eta(5)-C5H4P(S)Ph-2)(2)Ti(SPh)(2)]. C4H10O 7 indicate in both cases, a pseudo-tetrahedral arrangement around the titanium atom. The two SPh ligands in compound 7 are orientated in opposite sites of the TiS2 plane, which suggests an anti conformation for this molecule. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：27 / 33

页数：7

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