Novel MOF-Membrane for Molecular Sieving Predicted by IR-Diffusion Studies and Molecular Modeling

被引：226

作者：

Bux, Helge ^{[1
]}

Chmelik, Christian ^{[2
]}

van Baten, Jasper M. ^{[3
]}

Krishna, Rajamani ^{[3
]}

Caro, Juergen ^{[1
]}

机构：

[1] Leibniz Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany

[2] Univ Leipzig, Fac Phys & Geosci, D-04103 Leipzig, Germany

[3] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 42期

关键词：

METAL-ORGANIC FRAMEWORK; SEPARATION; CU-3(BTC)(2);

D O I：

10.1002/adma.201002066

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The predicted permeation selectivity of a binary gas mixture for a metal-organic framework ZIF-8 membrane is estimated from combined grand canonical Monte Carlo (GCMC) simulations and infrared microscopy (IRM) data and compared with permeation measurements on a ZIF-8 membrane. It is shown that membrane selectivity can be predicted and hence porous materials can be preselected for membrane applications thus saving time and effort in research and development.

引用

页码：4741 / +

页数：4

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