Asymmetric synthesis of chiral ferrocenyl fulleropyrrolidines as potential building blocks for new materials

被引：38

作者：

Mamane, V ^{[1
]}

Riant, O ^{[1
]}

机构：

[1] Univ Paris Sud, ICMO, Lab Catalyse Mol, F-91405 Orsay, France

来源：

TETRAHEDRON | 2001年 / 57卷 / 13期

关键词：

fullerenes; ferrocene; planar chirality;

D O I：

10.1016/S0040-4020(01)00066-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric [3+2] cycloaddition of chiral ferrocenyl substituted azomethine ylides to C-60 leads to the corresponding fulleropyrrolidines with high diastereoselectivities. This methodology has been applied to the preparation of a C-2-symmetric enantiopure fullerene dimer. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2555 / 2561

页数：7

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