Regio- and stereospecificity in radical cascade cyclizations of TMS-alkyne containing allyl bromomethyldimethylsilyl ethers

被引：3

作者：

Belval, F

Chavis, C

Fruchier, A

Montéro, JL

Lucas, M

机构：

[1] Univ Montpellier 2, Lab Chim Biomol, ESA 5074, F-34095 Montpellier 05, France

[2] Ecole Natl Super Chim, Chim Organ Lab, ESA 5076, F-34296 Montpellier, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(98)01107-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tandem radical cyclization of (E) and (Z) TMS-homopropargyl allyl bromomethyl-dimethylsilyl ethers is reported to provide an all-cis substituted vinylcyclopentanol 5. Regio- and stereospecificity are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5367 / 5368

页数：2

共 10 条

[1]

[Anonymous], J CHEM REV

[2]

BELVAL F, 1998, IN PRESS SYNTH COMMU, V28

[3] Tandem radical mediated 5-exo-trig, 6-endo-dig cyclization. Stereoselectivity, alpha-trimethylsilyl effect and the product spread .4. [J].