Synthesis and 19F NMR study of RF-oleic acid-F13

被引：13

作者：

Buchanan, GW ^{[1
]}

Smits, R ^{[1
]}

Munteanu, E ^{[1
]}

机构：

[1] Carleton Univ, Ottawa Carleton Chem Inst, Dept Chem, Ottawa, ON K1S 5B6, Canada

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2003年 / 123卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

terminally perfluorinated oleic acid; F-19; NMR;

D O I：

10.1016/S0022-1139(03)00162-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A seven-step synthesis of Z-13,13,14,14,15,15,16,16,17,17,18,18,18-tridecafluoro-octadec-9-enoic acid (oleic acid-F-13) is reported. The key step is a Wittig reaction to form the C9-C10 double bond with a Z:E isomeric ratio greater than 20:1. The F-19 nuclear magnetic resonance (NMR) spectrum is included and unambiguous assignments have been made with the aid of F-19-F-19 correlation NMR spectroscopy (COSY spectra). (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：255 / 259

页数：5

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