A highly active catalyst for CO oxidation at 298 K:: mononuclear AuIII complexes anchored to La2O3 nanoparticles

被引:66
作者
Fierro-Gonzalez, JC [1 ]
Bhirud, VA [1 ]
Gates, BC [1 ]
机构
[1] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
关键词
D O I
10.1039/b509629d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mononuclear La2O3-supported Au-III complexes synthesised from Au-III(CH3)(2)(C5H7O2) and characterised by X-ray absorption spectroscopy are highly active, stable CO oxidation catalysts at room temperature, demonstrating the importance of the support in stabilizing catalytically active gold species, which need not include zerovalent gold for high activity.
引用
收藏
页码:5275 / 5277
页数:3
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