Solubilities of p-tolylboronic acid, bromobenzene, and 4-phenyltoluene in carbon dioxide at elevated pressures

被引:5
作者
Leeke, GA [1 ]
Santos, RC
Seville, J
Al-Duri, B
Lee, CKY
Holmes, AB
机构
[1] Univ Birmingham, Dept Chem Engn, Ctr For & Formulat Engn, Birmingham B15 2TT, W Midlands, England
[2] Univ Cambridge, Dept Chem, Melville Lab Polymer Synthesis, Cambridge CB2 1EW, England
关键词
D O I
10.1021/je034051y
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubility data were determined for the first time for p-tolylboronic acid, bromobenzene, and 4-phenyl-toluene in carbon dioxide at (353 and 383) K and between pressures of (98 and 317) bar. Data were obtained using a cloud point apparatus fitted with an internal stirrer. The results were correlated using Chrastil's density based model.
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页码:48 / 52
页数:5
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