K-11[HSn3II((PW9O34)-O-VI)(2)]center dot 27H(2)O - Synthesis and structure

被引：14

作者：

Botar, A ^{[1
]}

Botar, B ^{[1
]}

Gili, P ^{[1
]}

Muller, A ^{[1
]}

Meyer, J ^{[1
]}

Bogge, H ^{[1
]}

Schmidtmann, M ^{[1
]}

机构：

[1] UNIV BIELEFELD,FAK CHEM,D-4800 BIELEFELD,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 09期

关键词：

tin(II)tungstophosphate; polyoxometalate;

D O I：

10.1002/zaac.19966220902

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

K-11[HSn3II((PW9O34)-O-VI)(2)]. 27 H2O 1 can be synthesized in an ''one-pot reaction'' from commercially obtainable educts (SnCl2; Na2HPO4 . 7 H2O, Na2WO4 . 2H(2)O) in high yields and has been characterized by elemental analysis, IR/Raman-, UV/Vis-spectroscopy as well as by X-ray crystal structure analysis. The example of 1 again demonstrates the validity of our working hypothesis, that polyoxometalates can be obtained by linking highly charged, transferable building blocks by cationic centres within the scope of an optimal charge control. For structural details see ''Inhaltsubersicht''.

引用

页码：1435 / 1440

页数：6

共 20 条

[1] HETEROPOLYANIONS AS NUCLEOPHILES .1. SYNTHESIS, CHARACTERIZATION, AND REACTIONS OF KEGGIN-TYPE AND DAWSON-TYPE TUNGSTOSTANNATES(II) [J].