Fabrication of CuS nanocrystals with various morphologies in the presence of a nonionic surfactant

被引:61
作者
Ji, HM [1 ]
Cao, JM [1 ]
Feng, J [1 ]
Chang, X [1 ]
Ma, XJ [1 ]
Liu, JS [1 ]
Zheng, MB [1 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Nanomat Res Inst, Nanjing 210016, Peoples R China
关键词
semiconductor; copper sulfide; nanocrystal; hydrothermal;
D O I
10.1016/j.matlet.2005.05.046
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Shape-controlled synthesis of CuS nanorods, nanoflakes, and flowerlike structures has been achieved simply in the presence of a nonionic surfactant polyethylene glycol (PEG20000) by adjusting hydrothermal temperature. The as-synthesized CuS nanocrystals were investigated by various techniques of XRD, TEM, SEM, and UV-vis spectra. The electron diffraction pattern indicated that the CuS nanoflakes were single crystals. In the process, the temperature and the surfactant PEG20000 were found to play important roles in determining the morphology of CuS nanocrystals. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:3169 / 3172
页数:4
相关论文
共 20 条
[1]   Synthesis of novel copper sulfide hollow spheres generated from copper (II)-thiourea complex [J].
Chen, XY ;
Wang, ZH ;
Wang, X ;
Zhang, R ;
Liu, XY ;
Lin, WJ ;
Qian, YT .
JOURNAL OF CRYSTAL GROWTH, 2004, 263 (1-4) :570-574
[2]  
CHIVERS T, 1996, J CHEM SOC DA, V7, P1185
[3]  
HULLIGER J, 1994, ANGEW CHEM INT EDIT, V33, P143, DOI 10.1002/anie.199401431
[4]   Biodegradable photo-crosslinked poly(ether-ester) networks for lubricious coatings [J].
Kim, BS ;
Hrkach, JS ;
Langer, R .
BIOMATERIALS, 2000, 21 (03) :259-265
[5]   Sonochemical process for the preparation of α-CuSe nanocrystals and flakes [J].
Li, HL ;
Zhu, YC ;
Avivi, S ;
Palchik, O ;
Xiong, JP ;
Koltypin, Y ;
Palchik, V ;
Gedanken, A .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3723-3727
[6]   A microwave assisted heating method for the preparation of copper sulfide nanorods [J].
Liao, XH ;
Chen, NY ;
Xu, S ;
Yang, SB ;
Zhu, JJ .
JOURNAL OF CRYSTAL GROWTH, 2003, 252 (04) :593-598
[7]   Microwave-assisted synthesis of one-dimensional nanostructures [J].
Lu, QY ;
Gao, F ;
Komarneni, S .
JOURNAL OF MATERIALS RESEARCH, 2004, 19 (06) :1649-1655
[8]   Synthesis of copper sulfide nanorod arrays on molecular templates [J].
Mao, GZ ;
Dong, WF ;
Kurth, DG ;
Mohwald, H .
NANO LETTERS, 2004, 4 (02) :249-252
[9]   Spray pyrolysis deposition of CuS thin films [J].
Nascu, C ;
Pop, I ;
Ionescu, V ;
Indrea, E ;
Bratu, I .
MATERIALS LETTERS, 1997, 32 (2-3) :73-77
[10]   Preparation of copper sulfide thin Layers by a single-source MOCVD process [J].
Nomura, R ;
Miyawaki, K ;
Toyosaki, T ;
Matsuda, H .
CHEMICAL VAPOR DEPOSITION, 1996, 2 (05) :174-&