Characterization of reactive intermediates in laser photolysis of nucleoside using of sodium salt anthraquinone-2-sulfonic acid as photosensitizer

被引：14

作者：

Ma, JH ^{[1
]}

Lin, WZ ^{[1
]}

Wang, WF ^{[1
]}

Han, ZH ^{[1
]}

Yao, SD ^{[1
]}

Lin, NY ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Nucl Res, Lab Radiat Chem, Shanghai 201800, Peoples R China

来源：

RADIATION PHYSICS AND CHEMISTRY | 1999年 / 54卷 / 05期

基金：

中国国家自然科学基金;

关键词：

laser photolysis; anthraquinone-2-sulfonate; triplet state; nucleoside; electron transfer;

D O I：

10.1016/S0969-806X(98)00300-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction of triplet state of sodium salt of anthraquinone-2-sulfonic acid (AQS) with nucleosides has been investigated in CH3CN using KrF(248 nm) laser flash photolysis. The transient absorption spectra and kinetics obtained from the interaction of triplet AQS and nucleoside demonstrated that the primary ionic radical pair, radical cation of nucleosides and radical anion of AQS has been detected simultaneously for the first time. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：491 / 497

页数：7

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