Kinetics of halogen oxide radicals in the stratosphere

被引：61

作者：

Bedjanian, Y ^{[1
]}

Poulet, G

机构：

[1] CNRS, Lab Combust & Syst Reactifs, F-45071 Orleans 2, France

[2] CNRS, Lab Phys & Chim Environm, F-45071 Orleans 2, France

[3] Univ Orleans, F-45071 Orleans 2, France

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 12期

关键词：

D O I：

10.1021/cr0205210

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The halogen oxide radicals and the gas-phase reactions involving XO radicals were analyzed. The potential role of XO radicals in stratospheric chemistry was also discussed. The XO radicals played an important role in the halogen-ozone interactions from the upper stratosphere to the marine boundary layer. For iodine, the lower overall rate constant significantly reduced the effectiveness of ozone destruction compared to chlorine. The impact of even very small injections of iodine in the stratosphere strongly depended on the products formed in the IO reactions with ClO and BrO, since the reaction channels could lead to ozone loss cycles.

引用

页码：4639 / 4655

页数：17

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