Hydrothermal synthesis and structure of a bi-capped Keggin polyoxoanion, [As2IIIAsVMo8V4IVO40]5-

被引：17

作者：

Luan, GY

Li, YG

Wang, EB ^{[1
]}

Han, ZB

Hu, CW

Hu, NH

Jia, HQ

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Jinlin, Peoples R China

[2] Acad Sinica, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 11期

基金：

中国国家自然科学基金;

关键词：

polyoxometalate; hydrothermal synthesis; crystal structure; bi-capped Keggin;

D O I：

10.1016/S1387-7003(01)00261-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, [NH3CH2CH2CH2NH2][NH3CH2CH2CH2NH3](2)[As-2(III) As-v Mo-8 V-4(IV) O-40] (.) 5H(2)O, was hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Crystal data: monoclinic, C2/c, a = 45.375(9) Angstrom, b = 11.774(2) Angstrom, c = 23.438(5) Angstrom, beta = 96.62(3)degrees. X-ray crystallographic study showed that the crystal structure was constructed by bi-capped alpha -Keggin fragments [(As2AsMo8V4O40)-As-III-Mo-v-O-IV](5-) polyoxoanion. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：632 / 634

页数：3

共 20 条

[1] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].