Ruthenium-indenylidene complexes: powerful tools for metathesis transformations

被引:152
作者
Boeda, Fabien [1 ]
Clavier, Herve [1 ]
Nolan, Steven P. [1 ]
机构
[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
关键词
D O I
10.1039/b718287b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ruthenium-indenylidene complexes represent a class of robust and efficient pre-catalysts for olefin metathesis reactions. In this feature article, we provide an overview of the various complexes belonging to this family and summarise their use in various applications. The relation between the nature of ancillary ligands around the metal coordination sphere of these complexes and their catalytic activity is also discussed.
引用
收藏
页码:2726 / 2740
页数:15
相关论文
共 90 条
[1]  
Adlhart C, 2002, ANGEW CHEM INT EDIT, V41, P4484, DOI 10.1002/1521-3773(20021202)41:23<4484::AID-ANIE4484>3.0.CO
[2]  
2-Q
[3]  
[Anonymous], [No title captured]
[4]   The metathesis reactions: from a historical perspective to recent developments [J].
Astruc, D .
NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) :42-56
[5]   Rate studies and mechanism of ring-closing olefin metathesis catalyzed by cationic ruthenium allenylidene arene complexes [J].
Bassetti, M ;
Centola, F .
ORGANOMETALLICS, 2003, 22 (22) :4459-4466
[6]  
Beligny S., 2006, N HETEROCYCLIC CARBE, P1
[7]   PERIODIC TRENDS IN CHARGE-DISTRIBUTION FOR TRANSITION-METAL COMPLEXES CONTAINING CATECHOLATE AND SEMIQUINONE LIGANDS - SYNTHETIC, PHYSICAL, AND STEREODYNAMIC PROPERTIES OF THE TRIS(3,5-DI-TERT-BUTYLQUINONE) COMPLEXES OF RUTHENIUM AND OSMIUM [J].
BHATTACHARYA, S ;
BOONE, SR ;
FOX, GA ;
PIERPONT, CG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) :1088-1096
[8]  
Bielawski CW, 2000, ANGEW CHEM INT EDIT, V39, P2903, DOI 10.1002/1521-3773(20000818)39:16<2903::AID-ANIE2903>3.0.CO
[9]  
2-Q
[10]   Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions [J].
Boeda, Fabien ;
Clavier, Herve ;
Jordaan, Margaritha ;
Meyer, Wolfgang H. ;
Nolan, Steven P. .
JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (01) :259-263