Trialkylsilyl-substituted pentalene ligands

被引：39

作者：

Cloke, FGN ^{[1
]}

Kuchta, MC ^{[1
]}

Harker, RM ^{[1
]}

Hitchcock, PB ^{[1
]}

Parry, JS ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 26期

关键词：

D O I：

10.1021/om000709e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [C8H6][Li(DME)](2) and chlorotrimethylsilane affords the trimethylsilyl-substituted dihydropentalene C8H6(SiMe3-1,4)(2), which may be deprotonated with (BuLi)-Bu-n in dimethoxyethane to give [C8H4(SiMe3-1,4)(2)][Li(DME)](2); the latter reacts with chlorotrimethylsilane to give C8H4(SiMe3-1,1',4,4')(4). Similarly, treatment of [C8H6][Li(DME)](2) with triisopropylsilyl triflate gives C8H6((SiPr3)-Pr-i-1,4)(2); deprotonation of the latter with KNH2 in, diethyl ether affords [C8H4((SiPr3)-Pr-i-1,4)2][K](2), which has been crystallographically characterized and exhibits a chain structure in the solid state.

引用

页码：5795 / 5798

页数：4

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