Independent switching of cubic nonlinear optical properties in a ruthenium alkynyl cruciform complex by employing protic and electrochemical stimuli

被引：79

作者：

Dalton, Gulliver T.

Cifuentes, Marie P.

Petrie, Simon

Stranger, Robert

Humphrey, Mark G. ^{[1
]}

Samoc, Marek

机构：

[1] Australian Natl Univ, Res Sch Phys Sci & Engn, Dept Chem, Canberra, ACT 0200, Australia

[2] Australian Natl Univ, Res Sch Phys Sci & Engn, Laser Phys Ctr, Canberra, ACT 0200, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 39期

关键词：

D O I：

10.1021/ja074205k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The quadrupolar ruthenium alkynyl cruciform complex is reversibly converted to tetravinylidene complex or tetraruthenium(III) tetracationic complex forms by protonation or oxidation, respectively; linear and nonlinear proto- and electrochromism studies reveal independent switching of NLO properties by the protic and electrochemical stimuli, respectively, aspects of which have been rationalized by theoretical studies.

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页码：11882 / +

页数：3

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