Synthesis and characterization of [NBu(4)][Pt-3(mu-PPh(2))(2)(C6F5)(5)]: An anionic cluster containing an unusual mu(3)-PPh(2) bridging system

被引：25

作者：

Alonso, E

Fornies, J

Fortuno, C

Martin, A

Orpen, AG

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[NBu(4)](2)[Pt-2(mu-PPh(2))(2)(C6F5)(4)] reacts with cis-[Pt(C6F5)(2)(thf)(2)] (1:2 molar ratio) yielding [NBu(4)] [Pt-3(mu-PPh(2))(2)(C6F5)(5)] which contains unusual mu(3)-PPh(1,2-eta(2)-Ph)-kappa(3)P phosphido and semi-bridging C6F5 ligands and two Pt-Pt bonds of length 2.899(1) and 2.772(1) Angstrom.

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页码：231 / 232

页数：2

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