Acid-induced Zn(II)-based metal-organic frameworks for encapsulation and sensitization of lanthanide cations

被引：11

作者：

He, Hongjie ^{[1
]}

Zhang, Lina ^{[2
]}

Deng, Mingli ^{[1
]}

Chen, Zhenxia ^{[1
]}

Ling, Yun ^{[1
]}

Chen, Jinxi ^{[2
]}

Zhou, Yaming ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 11期

关键词：

COORDINATION POLYMERS; SINGLE-CRYSTAL; SUPRAMOLECULAR ISOMERS; LUMINESCENCE; ADSORPTION; DIMENSIONALITY; TRANSFORMATION; TEMPERATURE; CHEMISTRY; DYES;

D O I：

10.1039/c5ce00083a

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Two Zn(II)-based metal-organic frameworks, namely, [Zn-3(Hbptc)(2)(DMF)(2)]center dot 2DMF(1) and [Zn-5(bptc)(3)center dot H2O)]((CH3)(2)NH2)(2)(2), (H(4)bptc = 3,3',5,5'-biphenyltetracarboxylic acid, DMF = N,N'-dimethylformamide), have been synthesized using different amounts of nitric acid under mixed-solvothermal conditions. 1 and 2 display different coordination geometries and donor ligands for the Zn2+ ions. In 1, only three carboxylic acid groups of H(4)bptc take part in the construction of the three-dimensional (3-D) framework with Zn2+, and one remains uncoordinated that can bind to other metal ions. Postsynthetic exchange of 1 with Ln(3+) cations demonstrates that 1 can effectively capture metal cations and sensitize the visible-emitting Ln(3+).

引用

页码：2294 / 2300

页数：7

共 61 条

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Zinc-Adeninate Metal-Organic Framework for Aqueous Encapsulation and Sensitization of Near-infrared and Visible Emitting Lanthanide Cations [J].