A Microporous Metal-Organic Framework with Immobilized -OH Functional Groups within the Pore Surfaces for Selective Gas Sorption

被引：96

作者：

Chen, Zhenxia ^{[1
,2
]}

Xiang, Shengchang ^{[2
]}

Arman, Hadi D. ^{[2
]}

Li, Peng ^{[2
]}

Tidrow, Steven ^{[3
]}

Zhao, Dongyuan ^{[1
]}

Chen, Banglin ^{[2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

[3] Univ Texas Pan Amer, Dept Phys & Geol, Edinburg, TX 78539 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 24期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

Copper; Microporous materials; Structure elucidation; Immobilization; Adsorption; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE; THERMAL-STABILITY; ADSORPTION; SEPARATION; DESIGN; H-2; ACETYLENE; STORAGE; CO2;

D O I：

10.1002/ejic.201000349

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new two-dimensional microporous metal-organic framework Cu(BDC-OH)(H2O)center dot 0.5DEF [abbreviation: Cu(BDC-OH); H2BDC-OH = 2-hydroxybenzene-1,4-dicarboxylic acid; DEF = diethylformamide] with functional OH groups on the pore surfaces was solvothermally synthesized and structurally characterized. The activated Cu(BDC-OH) exhibits a moderate Langmuir surface of 584 m(2)g(-1), a pore volume of 0.214 cm(3) g(-1), and C2H2/CH4 and CO2/CH4 selectivity of 6.7 and 9.3, respectively, at 296 K, thereby highlighting the promise for its application in gas separation.

引用

页码：3745 / 3749

页数：5

共 75 条

[1] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane [J].

Bae, Youn-Sang ;

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mirkin, Chad A. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

CHEMICAL COMMUNICATIONS, 2008, (35) :4135-4137

[2] Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification [J].

Bae, Youn-Sang ;

Farha, Omar K. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (15) :2131-2134

[3] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[4] Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework [J].

Barcia, Patrick S. ;

Zapata, Fatima ;

Silva, Jose A. C. ;

Rodrigues, Alirio E. ;

Chen, Banglin .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (22) :6101-6103

[5] A microporous metal-organic framework for separation of CO2/N2 and CO2/CH4 by fixed-bed adsorption [J].

Bastin, Laurent ;

Barcia, Patrick S. ;

Hurtado, Eric J. ;

Silva, Jose A. C. ;

Rodrigues, Alirio E. ;

Chen, Banglin .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (05) :1575-1581

[6] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 [J].

Bourrelly, S ;

Llewellyn, PL ;

Serre, C ;

Millange, F ;

Loiseau, T ;

Férey, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) :13519-13521

[7] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[8] Synthesis and Structure Characterization of Copper Terephthalate Metal-Organic Frameworks [J].

Carson, Cantwell G. ;

Hardcastle, Kenneth ;

Schwartz, Justin ;

Liu, Xiaotao ;

Hoffmann, Christina ;

Gerhardt, Rosario A. ;

Tannenbaum, Rina .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (16) :2338-2343

[9] Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material [J].

Chen, Banglin ;

Zhao, Xuebo ;

Putkham, Apipong ;

Hong, Kunlun ;

Lobkovsky, Emil B. ;

Hurtado, Eric J. ;

Fletcher, Ashleigh J. ;

Thomas, K. Mark .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6411-6423

[10] Selective gas sorption within a dynamic metal-organic framework [J].

Chen, Banglin ;

Ma, Shengqian ;

Hurtado, Eric J. ;

Lobkovsky, Emil B. ;

Liang, Chengdu ;

Zhu, Haoguo ;

Dai, Sheng .

INORGANIC CHEMISTRY, 2007, 46 (21) :8705-8709

← 1 2 3 4 5 6 7 8 →