A Microporous Metal-Organic Framework with Immobilized -OH Functional Groups within the Pore Surfaces for Selective Gas Sorption

被引：96

作者：

Chen, Zhenxia ^{[1
,2
]}

Xiang, Shengchang ^{[2
]}

Arman, Hadi D. ^{[2
]}

Li, Peng ^{[2
]}

Tidrow, Steven ^{[3
]}

Zhao, Dongyuan ^{[1
]}

Chen, Banglin ^{[2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

[3] Univ Texas Pan Amer, Dept Phys & Geol, Edinburg, TX 78539 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 24期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

Copper; Microporous materials; Structure elucidation; Immobilization; Adsorption; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE; THERMAL-STABILITY; ADSORPTION; SEPARATION; DESIGN; H-2; ACETYLENE; STORAGE; CO2;

D O I：

10.1002/ejic.201000349

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new two-dimensional microporous metal-organic framework Cu(BDC-OH)(H2O)center dot 0.5DEF [abbreviation: Cu(BDC-OH); H2BDC-OH = 2-hydroxybenzene-1,4-dicarboxylic acid; DEF = diethylformamide] with functional OH groups on the pore surfaces was solvothermally synthesized and structurally characterized. The activated Cu(BDC-OH) exhibits a moderate Langmuir surface of 584 m(2)g(-1), a pore volume of 0.214 cm(3) g(-1), and C2H2/CH4 and CO2/CH4 selectivity of 6.7 and 9.3, respectively, at 296 K, thereby highlighting the promise for its application in gas separation.

引用

页码：3745 / 3749

页数：5

共 75 条

[31]

KIM J, 2001, J AM CHEM SOC, V123, P8293

[32] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[33] Porous coordination-polymer crystals with gated channels specific for supercritical gases [J].

Kitaura, R ;

Seki, K ;

Akiyama, G ;

Kitagawa, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (04) :428-431

[34] Rational design and crystal structure determination of a 3-D metal-organic jungle-gym-like open framework [J].

Kitaura, R ;

Iwahori, F ;

Matsuda, R ;

Kitagawa, S ;

Kubota, Y ;

Takata, M ;

Kobayashi, TC .

INORGANIC CHEMISTRY, 2004, 43 (21) :6522-6524

[35] Metal-organic frameworks from copper dimers with cis- and trans-1,4-cyclohexanedicarboxylate and cis,cis-1,3,5-cyclohexanetricarboxylate [J].

Kumagai, Hitoshi ;

Akita-Tanaka, Motoko ;

Inoue, Katsuya ;

Takahashi, Kazuyuki ;

Kobayashi, Hayao ;

Vilminot, Serge ;

Kurmoo, Mohamedally .

INORGANIC CHEMISTRY, 2007, 46 (15) :5949-5956

[36] A comparison of the H2 sorption capacities of isostructural metal-organic frameworks with and without accessible metal sites:: [{Zn2(abtc)(dMf)2}3] and [{Cu2(abtc)(dMf)2}3] versus [{Cu2(abtc)}3] [J].

Lee, Yong-Gon ;

Moon, Hoi Ri ;

Cheon, Young Eun ;

Suh, Myunghyun Paik .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (40) :7741-7745

[37] Coordinatively unsaturated metal centers in the extended porous framework of Zn3(BDC)3.6CH3OH (BDC=1,4-benzenedicarboxylate) [J].

Li, HL ;

Davis, CE ;

Groy, TL ;

Kelley, DG ;

Yaghi, OM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (09) :2186-2187

[38] Selective gas adsorption and unique structural topology of a highly stable guest-free zeolite-type MOF material with N-rich chiral open channels [J].

Li, Jian-Rong ;

Tao, Ying ;

Yu, Qun ;

Bu, Xian-He ;

Sakamoto, Hirotoshi ;

Kitagawa, Susumu .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (09) :2771-2776

[39] Selective gas adsorption and separation in metal-organic frameworks [J].

Li, Jian-Rong ;

Kuppler, Ryan J. ;

Zhou, Hong-Cai .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1477-1504

[40] High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites [J].

Lin, Xiang ;

Telepeni, Irvin ;

Blake, Alexander J. ;

Dailly, Anne ;

Brown, Craig M. ;

Simmons, Jason M. ;

Zoppi, Marco ;

Walker, Gavin S. ;

Thomas, K. Mark ;

Mays, Timothy J. ;

Hubberstey, Peter ;

Champness, Neil R. ;

Schroeder, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (06) :2159-2171

← 1 2 3 4 5 6 7 8 →