Vinylogous Mannich-type reaction catalyzed by an iodine-substituted chiral phosphoric acid

被引：97

作者：

Akiyama, Takahiko ^{[1
]}

Honma, Yasuhiro ^{[1
]}

Itoh, Junji ^{[1
]}

Fuchibe, Kohei ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 03期

关键词：

addition to imines; amines; asymmetric catalysis; asymmetric synthesis; C-C bond formation; organic catalysis;

D O I：

10.1002/adsc.200700521

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

2-Trimethylsiloxyfuran underwent a vinylogous Mannich-type reaction with aldimines under the action of a new chiral phosphoric acid, bearing iodine on the 6,6'-positions of the binaphthyl group, as a chiral Bronsted acid to give gamma-butenolide derivatives bearing an amino functionality with high diastereo- and enantioselectivity.

引用

页码：399 / 402

页数：4

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