Evolution of copper(II) as a new alkene amination promoter and catalyst

被引：68

作者：

Chemler, Sherry R. ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 01期

基金：

美国国家卫生研究院;

关键词：

Alkene; Carboamination; Diamination; Aminooxygenation; Enantioselective; Copper; STEREOSELECTIVE-SYNTHESIS; INTRAMOLECULAR CARBOAMINATION; TANDEM CYCLIZATION; COUPLING REACTIONS; BOND FORMATION; DIAMINATION; RADICALS; ARYL; AMINOOXYGENATION; CARBOETHERIFICATION;

D O I：

10.1016/j.jorganchem.2010.08.041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(II) carboxylates and chiral copper(II) triflate center dot bis(oxazoline) complexes promote and catalyze intramolecular alkene carboamination, diamination and aminooxygenation reactions, creating an array of nitrogen heterocycles. High diastereoselectivity and enantioselectivity can be achieved in these transformations. This account reviews the discovery and development of these useful and interesting reactions. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：150 / 158

页数：9

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