Attempt to deposit carbon nitride films by electrodeposition from an organic liquid

被引：71

作者：

Fu, Q ^{[1
]}

Jiu, JT ^{[1
]}

Cai, K ^{[1
]}

Wang, H ^{[1
]}

Cao, CB ^{[1
]}

Zhu, HS ^{[1
]}

机构：

[1] Beijing Inst Technol, Res Ctr Mat Sci, Beijing 100081, Peoples R China

来源：

PHYSICAL REVIEW B | 1999年 / 59卷 / 03期

关键词：

D O I：

10.1103/PhysRevB.59.1693

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Carbon nitride films were synthesized by electrodeposition from an organic liquid on silicon substrates at temperatures lower than 80 degrees C. The N/C ratio in the films is about 0.25. The x-ray diffraction measurement indicates that the film contains some C3N4 polycrystalline phases. The Fourier-transform infrared spectroscopy, x-ray photoelectron spectroscopy, and Raman spectroscopy analyses suggest the presence of both single and double carbon-nitrogen bonds. The deposition mechanisms are also discussed. Our paper shows that the electrodeposition technique may hold some promise for synthesizing the metastable compound C3N4 in the liquid phase. [S0163-1829(99)05403-X].

引用

页码：1693 / 1696

页数：4

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