Biotransformation of (R)- and (S)-terpinen-4-ol by the Larvae of Common Cutworm (Spodoptera litura)

被引：18

作者：

Miyazawa, M ^{[1
]}

Kumagae, S ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 2001年 / 49卷 / 09期

关键词：

common cutworm; Spodoptera litura; biotransformation; terpinen-4-ol; (R)-p-menth-1-en-4,7-diol; (S)-p-menth-1-en-4,7-diol;

D O I：

10.1021/jf010273t

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

(R)-Terpinen-4-ol was mixed in an artificial diet at a concentration of 1 mg/g of diet, and the diet was fed to the last instar larvae of common cutworm (Spodoptera litura). Metabolites were recovered from frass and analyzed spectroscopically. (R)-Terpinen-4-ol was transformed mainly to (R)-p-menth-1-en-4,7-diol. Similarly, (S)-terpinen-4-ol was transformed mainly to (S)-p-menth-1-en-4,7-diol. The C-7 position (allylic methyl group) of (R)- and (S)-terpinen-4-ol was preferentially oxidized.

引用

页码：4312 / 4314

页数：3

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