Selective oxidation of carbohydrates on Nafion®-TEMPO-modified graphite felt electrodes

被引：43

作者：

Belgsir, EM

Schäfer, HJ

机构：

[1] Univ Poitiers, CNRS, UMR 6503, Catalyse Chim Organ Lab, F-86022 Poitiers, France

[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2001年 / 3卷 / 01期

关键词：

electrosynthesis; carbohydrates; oxidation; TEMPO;

D O I：

10.1016/S1388-2481(00)00137-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The TEMPO-mediated oxidation of carbohydrates was investigated iu heterogeneous conditions. The aminoxyl radicals were immobilised in a Nafion(R) film on graphite felt electrodes. This selectively gave rise to the corresponding uronic acids. Analytical results targeted towards the kinetics and the stability of the electrodes are also reported. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：32 / 35

页数：4

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