Porphyrin-based two-dimensional covalent organic frameworks: synchronized synthetic control of macroscopic structures and pore parameters

被引:211
作者
Feng, Xiao [1 ,2 ]
Chen, Long [1 ]
Dong, Yuping [2 ]
Jiang, Donglin [1 ,3 ]
机构
[1] Natl Inst Nat Sci, Dept Mat Mol Sci, Inst Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Beijing Inst Technol, Coll Mat Sci & Engn, Beijing 100081, Peoples R China
[3] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Tokyo, Japan
关键词
HYDROGEN STORAGE MATERIALS; RETICULAR SYNTHESIS; CRYSTALLINE; GENERATION;
D O I
10.1039/c0cc04386a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A two-dimensional porphyrin covalent organic framework is solvothermally synthesized and the macroscopic structure and pore parameters can be synthetically controlled. A remarkable and positive COF size effect on the pore parameters enables such structural control with a synchronized feature.
引用
收藏
页码:1979 / 1981
页数:3
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