Supramolecular Chemistry of Metalloporphyrins

被引:652
作者
Beletskaya, Irina [1 ]
Tyurin, Vladimir S. [1 ]
Tsivadze, Aslan Yu. [1 ]
Guilard, Roger [2 ]
Stern, Christine [2 ]
机构
[1] AN Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia
[2] Univ Bourgogne, Fac Sci Mirande, Inst Chim Mol, UMR 5260, F-21078 Dijon, France
基金
俄罗斯基础研究基金会;
关键词
LIGHT-HARVESTING COMPLEX; PHOTOSYNTHETIC REACTION-CENTER; TEMPLATE-DIRECTED SYNTHESIS; MIXED SUBSTRATE SUPERMOLECULES; PHOTOINDUCED ELECTRON-TRANSFER; CYCLIC PORPHYRIN OLIGOMERS; SELF-ORGANIZED PORPHYRIN; DOUBLE-DECKER COMPLEXES; SINGLE HYDROXO BRIDGE; COORDINATION POLYMERS;
D O I
10.1021/cr800247a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The supramolecular architectures where the key unit is metalloporphyrins, a most prevalent tetrapyrrolic macrocycle, is reviewed. The two sections of the study includes the design and structure of supramolecular systems and applications of porphyrin supramolecular complexes. The self-assembly of rotaxane and pseudorotaxane systems with a ruthenium carbonyl metalloporphyrin stopper unit is achieved with the support of the pyridyl groups as axial coordination ligands. The porphyrin nanoparticles, held together by hydrophobic and π-stacking effects, can be considered as self-organized systems that are governed by supramolecular chemistry principles. Work is conducted for the incorporation of porphyrins into larger complex and functional systems and for the encapsulation of porphyrins inside self-assembled coordination cages.
引用
收藏
页码:1659 / 1713
页数:55
相关论文
共 418 条
  • [1] AARON HS, 1979, TOP STEREOCHEM, V11, P1
  • [2] Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control
    Ahn, TK
    Kim, KS
    Kim, DY
    Noh, SB
    Aratani, N
    Ikeda, C
    Osuka, A
    Kim, D
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (05) : 1700 - 1704
  • [3] Electron and energy transfer in donor-acceptor systems with conjugated molecular bridges
    Albinsson, Bo
    Eng, Mattias P.
    Pettersson, Karin
    Winters, Mikael U.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (44) : 5847 - 5864
  • [4] Alessio E, 1996, CHEM COMMUN, P1411, DOI 10.1039/cc9960001411
  • [5] Porphyrin "flying-saucers": Solid state and solution structure of a novel pentameric array of axially-ligated canted porphyrins
    Alessio, E
    Geremia, S
    Mestroni, S
    Srnova, I
    Slouf, M
    Gianferrara, T
    Prodi, A
    [J]. INORGANIC CHEMISTRY, 1999, 38 (10) : 2527 - +
  • [6] Ordered supramolecular porphyrin arrays from a building block approach utilizing pyridylporphyrins and peripheral ruthenium complexes and identification of a new type of mixed-metal building block
    Alessio, E
    Macchi, M
    Heath, SL
    Marzilli, LG
    [J]. INORGANIC CHEMISTRY, 1997, 36 (24) : 5614 - 5623
  • [7] STRUCTURE OF THE REACTION CENTER FROM RHODOBACTER-SPHAEROIDES R-26 - THE COFACTORS .1.
    ALLEN, JP
    FEHER, G
    YEATES, TO
    KOMIYA, H
    REES, DC
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1987, 84 (16) : 5730 - 5734
  • [8] A self-assembled light-harvesting array of seven porphyrins in a wheel and spoke architecture
    Ambroise, A
    Li, JZ
    Yu, LH
    Lindsey, JS
    [J]. ORGANIC LETTERS, 2000, 2 (17) : 2563 - 2566
  • [9] LIGAND-BINDING BY BUTADIYNE-LINKED PORPHYRIA DIMERS, TRIMERS AND TETRAMERS
    ANDERSON, HL
    ANDERSON, S
    SANDERS, JKM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (18): : 2231 - 2245
  • [10] OCTATETRAYNE-LINKED PORPHYRINS - STRETCHED CYCLIC DIMERS AND TRIMERS WITH VERY SPACIOUS CAVITIES
    ANDERSON, HL
    WALTER, CJ
    VIDALFERRAN, A
    HAY, RA
    LOWDEN, PA
    SANDERS, JKM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1995, (18): : 2275 - 2279