Double Donor-Thiophene Dendron-Perylene Monoimide: Efficient Light-Harvesting Metal-Free Chromophore for Solid-State Dye-Sensitized Solar Cells

被引:20
作者
Wonneberger, Henrike [1 ]
Pschirer, Neil [3 ]
Bruder, Ingmar [3 ]
Schoeneboom, Jan [3 ]
Ma, Chang-Qi [2 ]
Erk, Peter [3 ]
Li, Chen [1 ]
Baeuerle, Peter [2 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Univ Ulm, Inst Organ Chem & Adv Mat 2, D-89081 Ulm, Germany
[3] BASF SE, D-67056 Ludwigshafen, Germany
关键词
donor-acceptor systems; dye-sensitized solar cells; organic photovoltaics; perylene; thiophene; CHARGE SEPARATION; HIGHLY EFFICIENT; ORGANIC-DYES; DESIGN;
D O I
10.1002/asia.201000895
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficient dye-namics: A highly efficient perylene sensitizer (ν=3.8%) for solid-state dye-sensitized solar cells was obtained. Key factors for this excellent photovoltaic performance are 1) careful balance of the orbital energies and color tuning, in order to achieve a broad spectrum with high absorptivity, 2) considerate steric architecture, and 3) a sound degree of orbital partitioning. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1744 / 1747
页数:4
相关论文
共 22 条
[1]  
[Anonymous], ANGEW CHEM
[2]  
Bessho T., 2010, Angew. Chem, V122, P6796
[3]   Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyrins [J].
Bessho, Takeru ;
Zakeeruddin, Shaik M. ;
Yeh, Chen-Yu ;
Diau, Eric Wei-Guang ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (37) :6646-6649
[4]   A Broadly Absorbing Perylene Dye for Solid-State Dye-Sensitized Solar Cells [J].
Cappel, Ute B. ;
Karlsson, Martin H. ;
Pschirer, Neil G. ;
Eickemeyer, Felix ;
Schoeneboom, Jan ;
Erk, Peter ;
Boschloo, Gerrit ;
Hagfeldt, Anders .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (33) :14595-14597
[5]   Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells [J].
Choi, Hyunbong ;
Baik, Chul ;
Kang, Sang Ook ;
Ko, Jaejung ;
Kang, Moon-Sung ;
Nazeeruddin, Md. K. ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :327-330
[6]   D-π-A Sensitizers for Dye-Sensitized Solar Cells: Linear vs Branched Oligothiophenes [J].
Fischer, Markus K. R. ;
Wenger, Sophie ;
Wang, Mingkui ;
Mishra, Amaresh ;
Zakeeruddin, Shaik M. ;
Gratzel, Michael ;
Baeuerle, Peter .
CHEMISTRY OF MATERIALS, 2010, 22 (05) :1836-1845
[7]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[8]   Molecular design of coumarin dyes for efficient dye-sensitized solar cells [J].
Hara, K ;
Sato, T ;
Katoh, R ;
Furube, A ;
Ohga, Y ;
Shinpo, A ;
Suga, S ;
Sayama, K ;
Sugihara, H ;
Arakawa, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (02) :597-606
[9]   Parameters influencing charge separation in solid-state dye-sensitized solar cells using novel hole conductors [J].
Kroeze, Jessica E. ;
Hirata, Narukuni ;
Schmidt-Mende, Lukas ;
Orizu, Charles ;
Ogier, Simon D. ;
Carr, Kathryn ;
Graetzel, Michael ;
Durrant, James R. .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (14) :1832-1838
[10]   Alkyl chain barriers for kinetic optimization in dye-sensitized solar cells [J].
Kroeze, Jessica E. ;
Hirata, Narukuni ;
Koops, Sara ;
Nazeeruddin, Md. K. ;
Schmidt-Mende, Lukas ;
Graetzel, Michael ;
Durrant, James R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) :16376-16383