Double Donor-Thiophene Dendron-Perylene Monoimide: Efficient Light-Harvesting Metal-Free Chromophore for Solid-State Dye-Sensitized Solar Cells

被引:20
作者
Wonneberger, Henrike [1 ]
Pschirer, Neil [3 ]
Bruder, Ingmar [3 ]
Schoeneboom, Jan [3 ]
Ma, Chang-Qi [2 ]
Erk, Peter [3 ]
Li, Chen [1 ]
Baeuerle, Peter [2 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Univ Ulm, Inst Organ Chem & Adv Mat 2, D-89081 Ulm, Germany
[3] BASF SE, D-67056 Ludwigshafen, Germany
关键词
donor-acceptor systems; dye-sensitized solar cells; organic photovoltaics; perylene; thiophene; CHARGE SEPARATION; HIGHLY EFFICIENT; ORGANIC-DYES; DESIGN;
D O I
10.1002/asia.201000895
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficient dye-namics: A highly efficient perylene sensitizer (ν=3.8%) for solid-state dye-sensitized solar cells was obtained. Key factors for this excellent photovoltaic performance are 1) careful balance of the orbital energies and color tuning, in order to achieve a broad spectrum with high absorptivity, 2) considerate steric architecture, and 3) a sound degree of orbital partitioning. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1744 / 1747
页数:4
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