Preparation of nanocrystalline nickel powders through hydrothermal-reduction method

被引：41

作者：

Wang, C

Zhang, XM

Qian, XF

Xie, Y

Wang, WZ

Qian, YT ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Anhui, Peoples R China

来源：

MATERIALS RESEARCH BULLETIN | 1998年 / 33卷 / 12期

关键词：

metals; chemical synthesis; X-ray diffraction;

D O I：

10.1016/S0025-5408(98)00180-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanocrystalline nickel powders were prepared in aqueous solution through a thermal-reduction process. The reductive atmosphere was produced from the disproportionation of white phosphorus in basic solution at 100 degrees C. X-ray diffraction (XRD), transmission electron microscopy (TEM), and chemical analysis were employed to characterize the products. XRD revealed that the nickel was single phase. TEM showed that the average particle size was about 26 nm. The purity of the as-prepared nickel was 99.6%, as determined from the spectrophotoscopy. The possible formation mechanism of nanocrystalline nickel is a reduction of nanocrystalline Ni(OH)(2). (C) 1999 Elsevier Science Ltd.

引用

页码：1747 / 1751

页数：5

共 13 条

[1] Nanoparticles of Ag, Au, Pd, and Cu produced by alcohol reduction of the salts [J].